Note on the Oxidation of Glutamic and Aspartic Acids by Means of Hydrogen Peroxide
نویسنده
چکیده
This reaction was found to occur in the case of glycocoll, alanin, or-amidovaleric acid, cz-amido-isovaleric acid, leucin and phenylalanin, and was of especial interest on account of the similarity of the products of oxidation with those obtained through some biochemical oxidative changes. The following experiments were undertaken in order to ascertain whether the reaction could be extended to the dibasic aminoacids. This was found to be the case. Glutamic acid proved to be readily oxidized when the ammonium salt was gently warmed with hydrogen peroxide, with liberation of ammonia and carbon dioxide and formation of large quantities of succinic acid. The reaction may be expressed as follows:
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